열역학 Phase Equilibria에 관한 이론 정리 및 P-X-Y, T-X-Y 을 매틀랩을 이용하여 구한 자료 입니다.
Phi-Gamma Approach 및 상평형에 대해 집중하였으며, 영문으로 작성되었습니다.
각 물질성분에 대해 실험자료와 매틀랩으로 구현된 시뮬레이션 자료를 Figure로 나타내며, 각 수치에 대한 Table을 작성하여 부록으로 실었습니다.
1. Introduction ··························································· 1
2. Procedure ······························································ 1
2.1 Phi-Gamma Approach ························································ 1
2.2 Phase Equilibria using an Equation of State ······························· 3
3. Results and Discussion ·············································· 4
3.1 Phi-Gamma Approach ························································ 5
1) Cyclohexane / Cyclohexnone ······································ 5
2) DME / N-Dodecane ················································· 6
3) DME / Toluene ······················································ 7
4) Chloroform / Methanol ············································· 8
5) Methylcyclopentane / Ethanol ····································· 9
6) Summary ···························································· 10
It is well known that there are various approaches to Vapor-Liquid Equilibrium, VLE, which
has been attracted considerable interest. Many binary systems have been developed by using
various equation of state (EOS) modeling, phi-gamma approach, and so on. In this project, we
studied the phi-gamma approach and the effect of equation of state. In this study, equations used
for VLE will be first discussed. Secondly, based on VLE calculation, we will compare the
calculate results with experimental data. In the comparison with experimental data, P-y(x) or Ty(
x) will be used for each system. The detailed data will be attached in Appendix. In addition, in
order to compare the calculated VLE model with the experimental data, we will choose a few
journals[1,2]that include the experimental data and reference books[3-5]